Thanks Brian. BeCu valve seats are a good match for aluminum heads and titanium valves. The BeCu seats have better thermal conductivity than nickel alloy seat materials. And BeCu alloy seats have a CTE that more closely matches aluminum head materials so it is easier to produce a secure interference fit. The BeCu alloys used for valve seats also respond to the work hardening effect produced on the surface that repeatedly contacts the valve face.
But as for Tommy Cookers comment about big interference fits between large diameter, thin radial section BeCu valve seats and aluminum heads being no problem, I would disagree a bit. Elastic modulus of the BeCu seat material versus aluminum is only one factor. There is also the relative section thicknesses of the seat versus that locally at the head to consider. If you look at some of the photos showing a section cut through the port, you'll note there is substantial head material surrounding the seat OD. So I would imagine the thick aluminum head is far stiffer radially than the thin BeCu seat at this interface.