gruntguru wrote:Tommy Cookers wrote:past experience means nothing here. with DI at 500 bar we do not need 10-15% surplus air for complete combustion of the fast-combusting race fuel maybe 2% surplus air is sufficient . . . . . but 10-15% surplus air is not needed for full combustion in 2014 F1 IMO
I have thought further about this and the reasons that 10-15% surplus air has always produced best BTE. I had always thought (perhaps like yourself) that it was all about mixing and that a stoichiometric mixture would produce best BTE if 100% mixed.
1. Even if that was the case, it is very unlikely that a DI system could achieve 100% mixing, in cylinder, at 10,500 rpm.
2. On reflection, a stoichiometric mixture would never achieve best BTE. Significant excess air is probably still needed to drive the combustion reactions predominantly in the direction of CO2 and H2O -
early in the power stroke. During the combustion phase reactions are constantly occuring in both directions and excess O2 helps to favour those headed in the forward direction (the exothermic ones) again -
early in the power stroke - heat produced later is less efficiently converted to work.
3. Likewise during combustion, some of the O2 is tied up in NOx production (more in fact than tailpipe emissions would suggest since some of these NOx species may dissociate later in the power stroke as the combustion products cool). Excess air is needed to make up the shortfall.
IIRC if you are now defending 10-15% lean rather than 30% lean, agreed that's easier
regarding your claim for the benefits to BTE of (10-15%) lean ......
textbooks present fuel:air cycle predicted benefits as rather optimistic compared to benefits measured in actual test engines
(in plots apparently derived from work in the 1960s by Edson or Edson & Taylor on old, carburetor-fueled engines)
these plots (eg in recent Ganesan and 60s Taylor books) present such benefits as measured to TE (not BTE)
with leaning the power at the piston falls but the friction does not ie there is little or less benefit to BTE
and restoring power while remaining lean requires a 'larger' engine ie increased massflow giving further disbenefit to BTE
having posted several times mentioning dissociation without any response .......
I cannot agree with your view that lean mixture is helpful in this regard, 80 years experience has shown otherwise
rising CO levels with stoichiometric (or richer) mixture strongly deter dissociation of CO2 back to CO eg according to Ganesan
aviation texts concur, also furnace design seems to agree and does not claim surplus air as you suggest to help over dissociation
Taylor discounts Nox as trivial and Ganesan ignores it
dissociation is primarily driven by a temperature threshold
though I speculated that fuel/additive etc chemistry can help , and suggested there is anyway a tradeoff of dissociation and HUCR
the Wright Turbo-Compound showed substantial dissociation at the port (even to CH4) in lean mixture cruise (F:A .057)
so presumably burning near the turbine
tbf even more dissociation at takeoff power, presumably due to the very high temperatures at the very high boost