DaveKillens wrote:The FIA technical regulations for 2011 state :
12.7 Tyre gases :
12.7.1 Tyres may only be inflated with air or nitrogen.
12.7.2 Any process the intent of which is to reduce the amount of moisture in the tyre and/or in its inflation gas is forbidden.
http://argent.fia.com/web/fia-public.ns ... 3-2011.pdf
That rule seems contradictory. I thought the main reason for using nitrogen was because bottled gases are dry so that contradicts 12.7.2.
Dry gases are less susceptible to pressure changes than damp gases. Having identified the need for a dry bottled gas, Nitrogen is used because it is the cheapest and inert.
Some folk say nitrogen helps the tyres last longer because the reduced oxygen reduces oxidisation of the tyre lining, plus nitrogen molecules are bigger, hence less likely to seep through the rubber. Also less water reduces corrosion of the wheel. However those issues of longevity are irrelevant for the short lifespan of an F1 tyre.
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For road cars.... when the tyre is put on the wheel it is full of air at 1 bar. If it is pressurised to 2.5 bar, then you are adding extra 1.5 times the tyre volume, hence the tyre contains 60% dry nitrogen and 40% wet air. Air at 20C with 75% humidity contains 13g water per m3, the dew point is 15C. This means water droplets will start to form in your tyre at 15C.
Dilute the tyre down to 40% air gives 5 g/m3, which has a dew point of 0C. So water droplets won’t form until it gets frosty.
Before you get too worried, a tyre only has 11 litres of air
http://www.club80-90syncro.co.uk/Syncro ... ulator.htm
So the amount of water in a tyre when filled with normal air at 13g/m3 is just 0.143g of water, ie 0.143ml. Hardly worth worrying about.
As for the oxygen molecules, the air is 79% nitrogen anyway. When those oxygen molecules leak or oxidise with the tyre lining you replace them with 79% nitrogen, so for every 100 molecules of leaking oxygen, you only put 21 back.
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The influence of humidity on expansion is an interesting one, I’ll let someone else take up that baton.